Found this from some old notes i have from the past, i its basically that the alternator will only produce what is demanded of it rather than continuosly providing enough power to fully charge the battery.
Current demand and flow:
If you have an alternator that can produce 120 amps of current (max) and the the total current demand from the electrical accessories (including the battery) is only 20 amps, the alternator will only produce the necessary current (20 amps) to maintain the target voltage (which is determined by the alternator's internal voltage regulator). Remember that the alternator monitors the electrical system's voltage. If the voltage starts to fall below the target voltage (approximately 13.8 volts depending on the alternator's design), the alternator produces more current to keep the voltage up. When the demand for current is low, the full current capacity of the alternator is not used/produced (a 120 amp alternator does not continuously produce 120 amps unless there is a sufficient current draw).
Charging System Basics:
The electrical system in an automobile is said to be a 12 volt system, but this is slightly misleading. The charging system in most cars will generally produce a voltage between 13.5 and 14.4 volts while the engine is running. It has to generate more voltage than the battery's rated voltage to overcome the internal resistance of the battery. This may seem strange, but the current needed to recharge the battery would not flow at all if the charging system's output voltage was the same as the battery voltage. A greater difference of potential (voltage) between the battery's voltage and the alternator's output voltage will provide a faster charging rate.
As long as the engine is running, all of the power for the accessories is delivered by the alternator. The battery is actually a load on the charging system. The only time that the battery would supply power with the engine running is when the current capacity of the alternator is exceeded or when engine is at a very low idle.
